Product ID:PHILLYCLAD 8 HARDENER
MSDS Date:10/16/1989
FSC:4730
NIIN:00-542-3359
Kit Part:Y
MSDS Number: BJFPM

ITW PHILADELPHIA RESINS CORP

130 COMMERCE DR
MONTGOMERYVILLE, PA 18936
US

Emergency Phone: 215-855-8450

Info Phone: 508-777-1100

Cage: ITWPH

MCJUNKIN CORPORATION

454 MONTGOMERYVILLE, PA 18936 US

Telephone: 508-777-1100

Cage: 2A443

TRIETHYLENETETRAMINE

CAS: 112-24-3

RTECS: YE6650000

Fraction By Weight: 30-60%

DIETHYLENE TRIAMINE

CAS: 111-40-0

RTECS: IE1225000

Fraction By Weight: 30-60%

OSHA PEL 1 PPM

ACGIH TLV: S, 1 PPM; 9192

LD50 LC50 Mixture:SEE SUPP DATA
Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:MAY CAUSE PAIN.MAY CAUSE
SEVERE IRRITATION WITH CORNEAL INJURY WHICH MAY RESULT IN PERMANENT
IMPAIRMENT OF VISION,EVEN BLINDNESS.SKIN:MAY CAUSE SEVERE SKIN
BURNS AND IS LIKELY TO CAUSE AN A LLERGIC REACTION.INHAL:MAY CAUSE
RESP SENSIT OR ASTHMA.INGEST:MAY CAUSE GASTROINTESTIONAL IRRITATION
OR ULCERATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:CHRONIC:REPEATED EXCESSIVE OVEREXPOSURE TO DETA
HAS CAUSED LIVER AND KIDNEY DAMAGE IN LAB ANIMALS.
Medical Cond Aggravated by Exposure:PREEXISTING SKIN AND EYE ALLERGIES
MAY INCREASE THE CHANGE OF DEVELOPING INCREASED ALLERGY SYMPTOMS
FROM EXPOSURE.

First Aid:EYES:FLUSH EYE W/CLEAN WATER FOR AT LEAST 15 MIN WHILE GENTLY
HOLDING EYELID OPEN.GET IMMED MEDICAL ATTN.SKIN:IMMED REMOVE
CONTAMD CLOTHING,AND WASH W/PLENTY OF SOAP AND WATER.GET MEDICAL
ATTN IF SYMP TOMS PERSIST.INHAL:REMOVE PATIENT TO FRESH
AIR.ADMINISTER OXYGEN IF BRTHING IS DFCLT.GET MEDICAL
ATTN.INGEST:DO NOT INDUCE VOMIT,GIVE PATIENT MILK OR WATER TO
DILUTE.IMMED CONSUL PHYSICIAN.

Flash Point Method:PMCC
Flash Point:245F,118C
Lower Limits:1.0
Upper Limits:3.6
Extinguishing Media:WATER, CO2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA&FULL PROTECTIVE
EQUIPMENT . IF A SPILL IS IGNITED,USE WATER SPRAY TO DISPERSE THE
VAPORS.
Unusual Fire/Explosion Hazard:NONE KNOWN

Spill Release Procedures:AVOID PERSONAL CONTACT. SCRAPE UP AS MUCH
MATERIAL AS POSSIBLE AND PLACE IN A SUITABLE, LABELED, CONTAINER
FOR WASTE DISPOSAL. RESIDUE MAY BE REMOVED USING A SAFETY SOLVENT.
Neutralizing Agent:SEE ABOVE

Handling and Storage Precautions:STORE IN COOL,DRY PLACE W/ADEQ
VENTILATION.KEEP AWAY FROM OPEN FLAME AND HIGH TEMP.PRACTICE GOOD
HOUSEKEEPING PROCEDURES TO AVOID SKIN CONTACT.
Other Precautions:HANDLE IN ACCORDANCE WITH THE HAZARD POTENTIAL OF
CURING AGENT.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE & CONCERN .
Ventilation:GENERAL MECHANICAL VENTILATION IS USUALLY ADEQUATE FOR MOST
INDUSTRIAL APPLICATIONS.
Protective Gloves:CHEMICAL RESISTANT RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:CLEAN LONG-SLEEVE AND LONG LEG CLOTHING,
EMERGENCY EYEWASH &DELUGE SHOWER
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
LD50 MIXTURE CONT'D:LD50(ORAL)1080 MG/KG(DETA)(RAT); LD50(ORAL)2500
MG/KG TRIETHYLENETETRAMINE(RAT)

Boiling Pt:B.P. Text:260
Vapor Pres:<1 AT 68F
Spec Gravity:1.18
pH:N/D
Evaporation Rate & Reference:<0.01
Solubility in Water:APPRECIABLE
Appearance and Odor:BLACK LIQUID WITH AMINE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS AND OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAMES.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, AND
OXIDES OF NITROGEN.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE
FEDERAL, STATE, AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.